Silvie Müller, Eckhard Ströfer, Maximilian Kohns, Kerstin Münnemann, Erik von Harbou, Hans Hasse

• Cold plasma is a partially ionized state of matter that unites high reactivity and mild conditions. Therefore, cold plasma reactors are intriguing for reaction engineering. In this work, a laboratory scale dielectric barrier discharge (DBD) cold plasma reactor was designed, set up, and used for studying the influence of the specific energy input (SEI) on the product spectrum of the partial oxidation of methane. In total, 23 experiments were carried out near ambient conditions with a molar reactant ratio of methane to oxygen of 2:1 at SEI between 0.3 and 6.0 J cm−3. The feed also contained argon at a mole fraction of 0.75 mol mol−1. The product stream was split into a fraction that was condensed in a cold trap and the remaining gaseous fraction. The latter was analyzed at-line in a gas chromatograph equipped with a dual column and two carrier gases. The condensed fraction was analyzed by qualitative and quantitative 1H and 13C NMR spectroscopy, Karl Fischer titration, and sodium sulfite titration. In the product stream, 16 components were identified and quantified: acetic acid, acetone, carbon dioxide, carbon monoxide, ethanol, ethane, ethene, ethylene glycol, formaldehyde, formic acid, hydrogen, methanol, methyl acetate, methyl hydroperoxide, methyl formate, and water. A univariant influence of the SEI on the conversions of methane and oxygen and the selectivities to the products was observed. The experimental results provided here are an asset for developing reaction kinetic models of the partial oxidation of methane in DBD plasma reactors.