Stereoselective Synthesis of 2-Oxyenamides**
- An improved route for the highly stereoselective synthesis of (Z)-2-oxyenamides is reported. The desired products can be accessed in only three steps from aminoacetaldehyde dimethyl acetal as common, readily available building block in a highly modular fashion. The improved procedure has been applied to the synthesis of various acylated and sufonylated oxyenamides. Mechanistic and theoretical studies provide a conclusive rationale for the observed stereoselectivities.
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| Author: | Sara-Cathrin Krieg, Jennifer Grimmer, Annika Maria Pick, Harald Kelm, Martin BreugstORCiD, Georg ManolikakesORCiD |
|---|---|
| URN: | urn:nbn:de:hbz:386-kluedo-80981 |
| DOI: | https://doi.org/10.1002/ejoc.202200772 |
| ISSN: | 1099-0690 |
| Parent Title (English): | European Journal of Organic Chemistry |
| Publisher: | Wiley |
| Document Type: | Article |
| Language of publication: | English |
| Date of Publication (online): | 2024/04/22 |
| Year of first Publication: | 2022 |
| Publishing Institution: | Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau |
| Date of the Publication (Server): | 2024/04/22 |
| Issue: | 2022/31 |
| Page Number: | 7 |
| Source: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202200772 |
| Faculties / Organisational entities: | Kaiserslautern - Fachbereich Chemie |
| DDC-Cassification: | 5 Naturwissenschaften und Mathematik / 540 Chemie |
| Collections: | Open-Access-Publikationsfonds |
| Licence (German): | Zweitveröffentlichung |