A Sustainable Ruthenium(III) Chloride Catalyzed Alcohol Oxidation
- Systematic optimization of the ruthenium-catalyzed oxidation of alcohols with tert-butyl hydroperoxide (TBHP) as the oxidizing agent was carried out. This resulted in the development of a sustainable protocol with a water/tert-butanol mixture as the solvent and an optimum use of the oxidizing agent by continuous addition with a syringe pump. The protocol is applicable for a broad variety of substrates. High yields of ketones and aldehydes are accessible.
| Author: | Nelly F. Nunheim, Werner R. ThielORCiD |
|---|---|
| URN: | urn:nbn:de:hbz:386-kluedo-88230 |
| DOI: | https://doi.org/10.1002/cctc.202301120 |
| ISSN: | 1867-3899 |
| Parent Title (English): | ChemCatChem |
| Publisher: | Wiley |
| Place of publication: | Weinheim |
| Editor: | Sandra González Gallardo, Juty Chen, Rose Puls |
| Document Type: | Article |
| Language of publication: | English |
| Date of Publication (online): | 2025/03/13 |
| Year of first Publication: | 2023 |
| Publishing Institution: | Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau |
| Date of the Publication (Server): | 2025/04/02 |
| Issue: | (2023) Vol.16 / 1 |
| Page Number: | 8 |
| Source: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202301120 |
| Faculties / Organisational entities: | Kaiserslautern - Fachbereich Chemie |
| DDC-Cassification: | 5 Naturwissenschaften und Mathematik / 540 Chemie |
| Collections: | Open-Access-Publikationsfonds |
| Licence (German): |  Creative Commons 4.0 - Namensnennung (CC BY 4.0) |